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Under typical physiological conditions, acetoacetic acid exists as its conjugate base, acetoacetate: AcCH 2 CO 2 H → AcCH 2 CO − 2 + H + Unbound acetoacetate is primarily produced by liver mitochondria from its thioester with coenzyme A (CoA): AcCH 2 C(O)−CoA + OH − → AcCH 2 CO − 2 + H−CoA. The acetoacetate-CoA itself is formed by ...
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When two acetyl-CoA molecules lose their -CoAs (or coenzyme A groups), they can form a (covalent) dimer called acetoacetate. β-hydroxybutyrate is a reduced form of acetoacetate, in which the ketone group is converted into an alcohol (or hydroxyl) group (see illustration on the right). Both are 4-carbon molecules that can readily be converted ...
Acetoacetic ester synthesis is a chemical reaction where ethyl acetoacetate is alkylated at the α-carbon to both carbonyl groups and then converted into a ketone, or more specifically an α-substituted acetone. This is very similar to malonic ester synthesis. Acetoacetic ester synthesis equation
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Download QR code; Print/export Download as PDF; Printable version; In other projects ... Aluminium acetoacetate is an antacid with the chemical formula C 18 H 27 AlO 9
The enzyme acetoacetyl-CoA hydrolase (EC 3.1.2.11) catalyzes the reaction . acetoacetyl-CoA + H 2 O CoA + acetoacetate. This enzyme belongs to the family of hydrolases, specifically those acting on thioester bonds.
New York-based cybersecurity firm Wiz says it has found a trove of sensitive data from the Chinese artificial intelligence startup DeepSeek inadvertently exposed to the open internet. In a blog ...