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The activation of these catalysts under H 2, produces cyclooctane, which is usually discarded or burnt: C 8 H 12 + 2 H 2 → C 8 H 16. Cyclooctane participates in no reactions except those typical of other saturated hydrocarbons, combustion and free radical halogenation. Work in 2009 on alkane functionalisation, using peroxides such as dicumyl ...
Possible isomers of cyclooctene. Cyclooctene is the cycloalkene with a formula C 8 H 14.Its molecule has a ring of 8 carbon atoms, connected by seven single bonds and one double bond.
trans-Cyclooctene was first synthesized on a preparatory scale by Arthur C. Cope with a Hofmann elimination reaction of N,N,N-trimethylcyclooctylammonium iodide. [10] The reaction gives a mixture of cis and trans isomers, and the trans isomer is selectively trapped as a complex with silver nitrate.
English: Cyclooctane boat-chair conformation. Source for name and structure: PW Pakes, TC Rounds, HL Strauss (1981). Conformations of cyclooctane and some related oxocanes. The Journal of Physical Chemistry. 85 (17): 2469–2475.
The Simplified Molecular Input Line Entry System (SMILES) is a specification in the form of a line notation for describing the structure of chemical species using short ASCII strings. SMILES strings can be imported by most molecule editors for conversion back into two-dimensional drawings or three-dimensional models of the molecules.
1,3,5,7-Cyclooctatetraene (COT) is an unsaturated derivative of cyclooctane, with the formula C 8 H 8.It is also known as [8]annulene.This polyunsaturated hydrocarbon is a colorless to light yellow flammable liquid at room temperature.
In the diagram below, the two ground state conformations exist in an equilibrium, with some difference in their ground state energies. Conformation B is lower in energy than conformation A, and while possessing a similar energy barrier to its transition state in a hypothetical reaction, thus the product formed is predominantly product B (P B ...
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