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One gram of 100% active chlorine bleach has the same bleaching power as one gram of elemental chlorine. The most common chlorine-based bleaches are: Sodium hypochlorite (NaClO), usually as a 3–6% solution in water, usually called "liquid bleach" or just "bleach". Historically called "Javel water" (French: eau de Javel).
Sodium hypochlorite solutions, such as liquid bleach, will release toxic chlorine gas when mixed with an acid, such as hydrochloric acid or vinegar. A 2008 study indicated that sodium hypochlorite and organic chemicals (e.g., surfactants, fragrances) contained in several household cleaning products can react to generate chlorinated organic ...
The hypochlorite anion and chlorine are in equilibrium in water; the position of the equilibrium is pH dependent and low pH (acidic) favors chlorine, [11] Cl 2 + H 2 O ⇌ 2H + + Cl − + ClO −. A hypochlorite bleach can react violently with hydrogen peroxide and produce oxygen gas: H 2 O 2 (aq) + NaOCl (aq) → NaCl (aq) + H 2 O(l) + O 2 (g)
When acids are added to aqueous salts of hypochlorous acid (such as sodium hypochlorite in commercial bleach solution), the resultant reaction is driven to the left, and chlorine gas is formed. Thus, the formation of stable hypochlorite bleaches is facilitated by dissolving chlorine gas into basic water solutions, such as sodium hydroxide.
The resulting liquid, known as "Eau de Javel" ("Javel water"), was a weak solution of sodium hypochlorite. Another strong chlorine oxidant and bleach which he investigated and was the first to produce, potassium chlorate (KClO 3), is known as Berthollet's Salt. Berthollet first determined the elemental composition of the gas ammonia, in 1785.
Hypochlorite salts formed by the reaction between chlorine and alkali and alkaline earth metal hydroxides. The reaction is performed at close to room temperature to suppress the formation of chlorates. This process is widely used for the industrial production of sodium hypochlorite (NaClO) and calcium hypochlorite (Ca(ClO) 2).
While I know the vinegar to use for cleaning isn’t balsamic, raspberry, or red wine vinegar, I always thought white distilled vinegar (and occasionally apple cider vinegar), was cleaning vinegar ...
Manual Control Chlorinator for the liquefaction of chlorine for water purification, early 20th century. From Chlorination of Water by Joseph Race, 1918. The first continuous use of chlorine in the United States for disinfection took place in 1908 at Boonton Reservoir (on the Rockaway River), which served as the supply for Jersey City, New ...