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  2. Petersen matrix - Wikipedia

    en.wikipedia.org/wiki/Petersen_matrix

    A system of a third order reaction followed by a Michaelis–Menten enzyme reaction. + + + where the reagents A and B combine forming the substrate S (S = AB 2), which with the help of enzyme E is transformed into the product P. Production rates for each substance is:

  3. Rate equation - Wikipedia

    en.wikipedia.org/wiki/Rate_equation

    A reaction can also have an undefined reaction order with respect to a reactant if the rate is not simply proportional to some power of the concentration of that reactant; for example, one cannot talk about reaction order in the rate equation for a bimolecular reaction between adsorbed molecules:

  4. Molecularity - Wikipedia

    en.wikipedia.org/wiki/Molecularity

    These reactions frequently have a pressure and temperature dependence region of transition between second and third order kinetics. [ 8 ] Catalytic reactions are often three-component, but in practice a complex of the starting materials is first formed and the rate-determining step is the reaction of this complex into products, not an ...

  5. Birch reduction - Wikipedia

    en.wikipedia.org/wiki/Birch_reduction

    The reaction is known to be third order – first order in the aromatic, first order in the alkali metal, and first order in the alcohol. [4] This requires that the rate-limiting step be the conversion of radical anion B to the cyclohexadienyl radical C. Birch reduction of anisole. That step also determines the structure of the product.

  6. Passerini reaction - Wikipedia

    en.wikipedia.org/wiki/Passerini_reaction

    The Passerini reaction is a chemical reaction involving an isocyanide, ... It is a third order reaction; first order in each of the reactants. ... For example ...

  7. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...

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  9. Continuous stirred-tank reactor - Wikipedia

    en.wikipedia.org/wiki/Continuous_stirred-tank...

    n th-order reaction (r = kC A n), where k is the reaction rate constant, C A is the concentration of species A, and n is the order of the reaction; isothermal conditions, or constant temperature (k is constant) single, irreversible reaction (ν A = −1) All reactant A is converted to products via chemical reaction; N A = C A V