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Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist between two different elements: for example, in a carbonyl group between a carbon atom and an oxygen atom. Other common double bonds are found in azo compounds (N=N), imines (C=N), and sulfoxides (S=O). In a skeletal formula, a double bond ...
In fact, the carbon atoms in the single bond need not be of the same hybridization. Carbon atoms can also form double bonds in compounds called alkenes or triple bonds in compounds called alkynes. A double bond is formed with an sp 2-hybridized orbital and a p-orbital that is not involved in the hybridization. A triple bond is formed with an sp ...
In 1 H NMR spectroscopy, the hydrogen bonded to the carbon adjacent to double bonds will give a δ H of 4.5–6.5 ppm. The double bond will also deshield the hydrogen attached to the carbons adjacent to sp 2 carbons, and this generates δ H =1.6–2. ppm peaks. [14] Cis/trans isomers are distinguishable due to different J-coupling effect.
The polarity of C=O bond also enhances the acidity of any adjacent C-H bonds. Due to the positive charge on carbon and the negative charge on oxygen, carbonyl groups are subject to additions and/or nucleophilic attacks. A variety of nucleophiles attack, breaking the carbon-oxygen double bond, and leading to addition-elimination reactions.
Unsaturated hydrocarbons, which have one or more double or triple bonds between carbon atoms. Those with one or more double bonds are called alkenes. Those with one double bond have the formula C n H 2n (assuming non-cyclic structures). [1]: 628 Those containing triple bonds are called alkyne. Those with one triple bond have the formula C n H ...
A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially closed mesh, with fused rings of five to six atoms. The molecules may have hollow sphere- and ellipsoid-like forms, tubes, or other shapes.
Although such compounds are not intrinsically unstable, they instead tend to dimerize or even polymerize. [1] Moreover, the multiple bonds of the elements with n =2 are much stronger than usual, because lone pair repulsion weakens their sigma bonding but not their pi bonding.) [ 2 ] An example is the rapid polymerization that occurs upon ...
Carbon compounds are defined as chemical substances containing carbon. [1] [2] More compounds of carbon exist than any other chemical element except for hydrogen. Organic carbon compounds are far more numerous than inorganic carbon compounds. In general bonds of carbon with other elements are covalent bonds.