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Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane ( P 2 H 4 ).
The parent compound of the phosphines is PH 3, called phosphine in the US and British Commonwealth, but phosphane elsewhere. [9] Replacement of one or more hydrogen centers by an organic substituents (alkyl, aryl), gives PH 3−x R x, an organophosphine, generally referred to as phosphines.
The latter is a common feature of the chemistry of phosphorus. As a result, the lone pair of trimethylphosphine has predominantly s-character as is the case for phosphine, PH 3. [10] Tertiary phosphines are pyramidal. When the organic substituents all differ, the phosphine is chiral and
Since 1988, it has been called Group 15 by the IUPAC. Before that, in America it was called Group VA, owing to a text by H. C. Deming and the Sargent-Welch Scientific Company, while in Europe it was called Group VB, which the IUPAC had recommended in 1970. [2] (Pronounced "group five A" and "group five B"; "V" is the Roman numeral 5).
Phosphines or phosphanes are phosphorus compounds derived from phosphine and have the general structure R 3 P. For the nitrogen analogues, please see Category:Inorganic amines . Wikimedia Commons has media related to Phosphines .
In chemistry, the term phosphonium (more obscurely: phosphinium) describes polyatomic cations with the chemical formula PR + 4 (where R is a hydrogen or an alkyl, aryl, or halide group). These cations have tetrahedral structures. The salts are generally colorless or take the color of the anions. [1]
Phosphine (PH 3) and its organic derivatives (PR 3) are structural analogues of ammonia (NH 3), but the bond angles at phosphorus are closer to 90° for phosphine and its organic derivatives. Phosphine is an ill-smelling, toxic gas. Phosphorus has an oxidation number of −3 in phosphine. Phosphine is produced by hydrolysis of calcium phosphide ...
It is also called phosphabenzene and belongs to the phosphaalkene class. It is a colorless liquid that is mainly of interest in research. Phosphorine is an air-sensitive oil [2] but is otherwise stable when handled using air-free techniques (however, substituted derivatives can often be handled under air without risk of decomposition).