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Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude. The change of atmospheric pressure with altitude can be obtained from this equation: [2]
PM is most usually (but not always) expressed as mg/m 3 of air or other gas at a specified temperature and pressure. For gases, volume percent = mole percent 1 volume percent = 10,000 ppmv (i.e., parts per million by volume) with a million being defined as 10 6 .
However, the names of all SI mass units are based on gram, rather than on kilogram; thus 10 3 kg is a megagram (10 6 g), not a *kilokilogram. The tonne (t) is an SI-compatible unit of mass equal to a megagram (Mg), or 10 3 kg. The unit is in common use for masses above about 10 3 kg and is often used with SI prefixes.
In unit systems where force is a derived unit, like in SI units, g c is equal to 1. In unit systems where force is a primary unit, like in imperial and US customary measurement systems , g c may or may not equal 1 depending on the units used, and value other than 1 may be required to obtain correct results. [ 2 ]
For example, the conversion factor between a mass fraction of 1 ppb and a mole fraction of 1 ppb is about 4.7 for the greenhouse gas CFC-11 in air (Molar mass of CFC-11 / Mean molar mass of air = 137.368 / 28.97 = 4.74). For volume fraction, the suffix "V" or "v" is sometimes appended to the parts-per notation (e.g. ppmV, ppbv, pptv).
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