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Blast furnace gas (BFG) [1] is a by-product of blast furnaces that is generated when the iron ore is reduced with coke to metallic iron. It has a very low heating value , about 3.5 MJ/m 3 (93 BTU /cu.ft), [ 2 ] because it consists of about 51 vol% nitrogen and 22 vol% carbon dioxide , which are not flammable.
The hot blast temperature can be from 900 to 1,300 °C (1,650 to 2,370 °F) depending on the stove design and condition. ... natural gas) use in blast furnaces is a ...
Gas / Fuels Flame temperature Propane in air 1980 °C 3596 °F ... Coal in air (blast furnace) 1900 °C 3452 °F Cyanogen (C 2 N 2) in oxygen 4525 °C 8177 °F
The coking plant that feeds a battery of blast furnaces is just as expensive as the blast furnace and requires a specific quality of coal. [ 64 ] [ 65 ] Conversely, many direct-reduction processes are disadvantaged by the costly transformation of ore into pellets: these cost on average 70% more than raw ore. [ 66 ]
James Beaumont Neilson, previously foreman at Glasgow gas works, invented the system of preheating the blast for a furnace.He found that by increasing the temperature of the incoming air to 149 °C (300 °F), he could reduce the fuel consumption from 8.06 tons of coal to 5.16 tons of coal per ton of produced iron with further reductions at even higher temperatures. [4]
For blast furnaces, direct reduction corresponds to the reduction of oxides by the carbon in the coke. However, in practice, direct reduction only plays a significant role in the final stage of iron reduction in a blast furnace, by helping to reduce wustite (FeO) to iron. In this case, the chemical reaction can be trivially described as follows ...
The hot blast pumps hot air into the blast furnace. The hot blast temperature ranges from 900 to 1,300 °C (1,650 to 2,370 °F) depending on the design and condition. Oil, tar , natural gas, powdered coal and oxygen can be injected to combine with the coke to release additional energy and increase the percentage of reducing gases present ...
In the temperature ranges commonly used, the metal and the oxide are in a condensed state (solid or liquid), and oxygen is a gas with a much larger molar entropy. For the oxidation of each metal, the dominant contribution to the entropy change (ΔS) is the removal of 1 ⁄ 2 mol O 2, so that ΔS is negative and roughly equal for all metals.