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The thermal conductivity detector (TCD), also known as a katharometer, is a bulk property detector and a chemical specific detector commonly used in gas chromatography. [1] This detector senses changes in the thermal conductivity of the column eluent and compares it to a reference flow of carrier gas. Since most compounds have a thermal ...
Thermal radiation () End losses through the support structures; A heated metal wire (sensor wire, or simply sensor) suspended in a gas will lose heat to the gas as its molecules collide with the wire and remove heat. If the gas pressure is reduced, the number of molecules present will fall proportionately and the wire will lose heat more slowly.
The heat generated dissipates into the sample on both sides of the sensor, at a rate depending on the thermal transport properties of the material. By recording temperature vs. time response in the sensor, the thermal conductivity, thermal diffusivity and specific heat capacity of the material can be calculated.
Furthermore, because of the very small measuring time (1 s) there is no convection present in the measurements and only the thermal conductivity of the fluid is measured with very high accuracy. Most of the transient hot wire sensors used in academia consist of two identical very thin wires with only difference in the length. [1]
Time-domain thermoreflectance (TDTR) is a method by which the thermal properties of a material can be measured, most importantly thermal conductivity. This method can be applied most notably to thin film materials (up to hundreds of nanometers thick), which have properties that vary greatly when compared to the same materials in bulk. The idea ...
A pellistor is a solid-state device [1] used to detect gases which are either combustible or which have a significant difference in thermal conductivity to that of air. The word "pellistor" is a combination of pellet and resistor.
Very high thermal conductivity measurements up to 22,600 w m −1 K −1 were reported by Fenton, E.W., Rogers, J.S. and Woods, S.D. in reference 570 on page 1458, 41, 2026–33, 1963. The data is listed on pages 6 through 8 and graphed on page 1 where Fenton and company are on curves 63 and 64.
Portable instruments for the analysis of helium content of breathing gas mixtures may be based on a thermal conductivity sensor (katharometer). These sensors can be very stable and maintenance free and also highly reliable and accurate. [1] A typical thermal helium analyser comprises two chambers, each with an identical thermal conductivity sensor.
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