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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
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2 hc(o)nh 2 + 2h 2 o + h 2 so 4 → 2hco 2 h + (nh 4) 2 so 4 A disadvantage of this approach is the need to dispose of the ammonium sulfate byproduct. This problem has led some manufacturers to develop energy-efficient methods of separating formic acid from the excess water used in direct hydrolysis.
For example, NH 3 is a Lewis base, because it can donate its lone pair of electrons. Trimethylborane [(CH 3) 3 B] is a Lewis acid as it is capable of accepting a lone pair. In a Lewis adduct, the Lewis acid and base share an electron pair furnished by the Lewis base, forming a dative bond. [1]
The cornerstone of classical bonding theories is the Lewis structure, published by G. N. Lewis in 1916 and continuing to be widely taught and disseminated to this day. [3] In this theory, the electrons in bonds are believed to pair up, forming electron pairs which result in the binding of nuclei .
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In the context of NBO, the true density operator Γ represents the NBOs of an idealized natural Lewis structure. [1] [3] Once NRT has generated a set of density operators, Γ α, for localized resonance structures, α, a least-squares variational functional is employed to quantify the resonance weights of each structure. [1]
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