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MO diagram of dimolybdenum. A sextuple bond is a type of covalent bond involving 12 bonding electrons and in which the bond order is 6. The only known molecules with true sextuple bonds are the diatomic dimolybdenum (Mo 2) and ditungsten (W 2), which exist in the gaseous phase and have boiling points of 4,639 °C (8,382 °F) and 5,930 °C (10,710 °F) respectively.
For instance, in dioxygen the 3σ g MO can be roughly considered to be formed from interaction of oxygen 2p z AOs only. It is found to be lower in energy than the 1π u MO, both experimentally and from more sophisticated computational models, so that the expected order of filling is the 3σ g before the 1π u . [ 10 ]
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Mo 2 (O 2 CCH 3) 4 is prepared by treating molybdenum hexacarbonyl (Mo(CO) 6) with acetic acid.The process strips CO ligands from the hexacarbonyl and results in the oxidation of Mo(0) to Mo(II).