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In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus.The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus.
An electron shell is the set of allowed states that share the same principal quantum number, n, that electrons may occupy. In each term of an electron configuration, n is the positive integer that precedes each orbital letter (helium's electron configuration is 1s 2, therefore n = 1, and the orbital contains two
The rule then predicts the electron configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 9 4s 2, abbreviated [Ar] 3d 9 4s 2 where [Ar] denotes the configuration of argon, the preceding noble gas. However, the measured electron configuration of the copper atom is [Ar] 3d 10 4s 1. By filling the 3d subshell, copper can be in a lower energy state.
Fundamentally, an atomic orbital is a one-electron wave function, even though many electrons are not in one-electron atoms, and so the one-electron view is an approximation. When thinking about orbitals, we are often given an orbital visualization heavily influenced by the Hartree–Fock approximation, which is one way to reduce the ...
The wider the electron shells are in space, the weaker is the electric interaction between the electrons and the nucleus due to screening. Further, because of differences in orbital penetration, we can order the screening strength, S, that electrons in a given orbital (s, p, d, or f) provide to the rest of the electrons thusly: > > > ().
However, the s states in the L, M, and N shells (i.e., the 2s, 3s, and 4s states) are also able to couple to the nuclear fields and cause IC electron ejections from those shells (called L or M or N internal conversion). Ratios of K-shell to other L, M, or N shell internal conversion probabilities for various nuclides have been prepared. [3]
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