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Blast furnace gas (BFG) [1] is a by-product of blast furnaces that is generated when the iron ore is reduced with coke to metallic iron. It has a very low heating value , about 3.5 MJ/m 3 (93 BTU /cu.ft), [ 2 ] because it consists of about 51 vol% nitrogen and 22 vol% carbon dioxide , which are not flammable.
Blast furnaces differ from bloomeries and reverberatory furnaces in that in a blast furnace, flue gas is in direct contact with the ore and iron, allowing carbon monoxide to diffuse into the ore and reduce the iron oxide. The blast furnace operates as a countercurrent exchange process whereas a bloomery does not.
In iron ore smelting, haematite gets reduced at the top of the furnace, where temperature is in the range 600 – 700 °C. The Ellingham diagram indicates that in this range carbon monoxide acts as a stronger reducing agent than carbon since the process 2 CO + O 2 → 2 CO 2. has a more-negative free energy change than the process: 2 C + O 2 ...
The constant volume adiabatic flame temperature is the temperature that results from a complete combustion process that occurs without any work, heat transfer or changes in kinetic or potential energy. Its temperature is higher than in the constant pressure process because no energy is utilized to change the volume of the system (i.e., generate ...
Consider a gas in cylinder with a free floating piston resting on top of a volume of gas V 1 at a temperature T 1. If the gas is heated so that the temperature of the gas goes up to T 2 while the piston is allowed to rise to V 2 as in Figure 1, then the pressure is kept the same in this process due to the free floating piston being allowed to ...
For blast furnaces, direct reduction corresponds to the reduction of oxides by the carbon in the coke. However, in practice, direct reduction only plays a significant role in the final stage of iron reduction in a blast furnace, by helping to reduce wustite (FeO) to iron. In this case, the chemical reaction can be trivially described as follows ...
As blast furnaces re-equipped after World War II, the favoured power source was either the diesel engine or the electric motor. These both had a rotary output, which worked well with contemporary developments in centrifugal fans capable of handling the huge volumes of air. Although the reciprocating steam blowing engine continued where it was ...
James Beaumont Neilson, previously foreman at Glasgow gas works, invented the system of preheating the blast for a furnace.He found that by increasing the temperature of the incoming air to 149 °C (300 °F), he could reduce the fuel consumption from 8.06 tons of coal to 5.16 tons of coal per ton of produced iron with further reductions at even higher temperatures. [4]