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One of the fundamental thermodynamic equations is the description of thermodynamic work in analogy to mechanical work, or weight lifted through an elevation against gravity, as defined in 1824 by French physicist Sadi Carnot. Carnot used the phrase motive power for work.
The ancient Greek understanding of physics was limited to the statics of simple machines (the balance of forces), and did not include dynamics or the concept of work. During the Renaissance the dynamics of the Mechanical Powers, as the simple machines were called, began to be studied from the standpoint of how far they could lift a load, in addition to the force they could apply, leading ...
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
There are many types of conjugate variables, depending on the type of work a certain system is doing (or is being subjected to). Examples of canonically conjugate variables include the following: Time and frequency : the longer a musical note is sustained, the more precisely we know its frequency, but it spans a longer duration and is thus a ...
Power is the rate with respect to time at which work is done; it is the time derivative of work: =, where P is power, W is work, and t is time. We will now show that the mechanical power generated by a force F on a body moving at the velocity v can be expressed as the product: P = d W d t = F ⋅ v {\displaystyle P={\frac {dW}{dt}}=\mathbf {F ...
Transfers of energy as work, or as heat, or of matter, between the system and the surroundings, take place through the walls, according to their respective permeabilities. Matter or energy that pass across the boundary so as to effect a change in the internal energy of the system need to be accounted for in the energy balance equation.
Every conservative force has a potential energy. By following two principles one can consistently assign a non-relative value to U: Wherever the force is zero, its potential energy is defined to be zero as well. Whenever the force does work, potential energy is lost.
The work done on the system is defined and measured by changes in mechanical or quasi-mechanical variables external to the system. Physically, adiabatic transfer of energy as work requires the existence of adiabatic enclosures. For instance, in Joule's experiment, the initial system is a tank of water with a paddle wheel inside.