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The trigonal crystal system consists of the 5 point groups that have a single three-fold rotation axis, which includes space groups 143 to 167. These 5 point groups have 7 corresponding space groups (denoted by R) assigned to the rhombohedral lattice system and 18 corresponding space groups (denoted by P) assigned to the hexagonal lattice system.
Crystals can be classified in three ways: lattice systems, crystal systems and crystal families. The various classifications are often confused: in particular the trigonal crystal system is often confused with the rhombohedral lattice system, and the term "crystal system" is sometimes used to mean "lattice system" or "crystal family".
In geometry, a rhombohedron (also called a rhombic hexahedron [1] [2] or, inaccurately, a rhomboid [a]) is a special case of a parallelepiped in which all six faces are congruent rhombi. [3] It can be used to define the rhombohedral lattice system , a honeycomb with rhombohedral cells.
In monoclinic, trigonal, tetragonal, and hexagonal systems there is one unique axis (sometimes called the principal axis) which has higher rotational symmetry than the other two axes. The basal plane is the plane perpendicular to the principal axis in these crystal systems.
Rhombohedral: R 3 m (No. 166) 105 (rh.) 315 (hex.) Partly due to its complexity, whether this structure is the ground state of Boron has not been fully settled. α-As: A7: Rhombohedral: R 3 m (No. 166) 2 (rh.) 6 (hex.) in grey metallic form, each As atom has 3 neighbours in the same sheet at 251.7pm; 3 in adjacent sheet at 312.0 pm. [18]
In geometry, a trigonal trapezohedron is a polyhedron with six congruent quadrilateral faces, which may be scalene or rhomboid. [1] [2] The variety with rhombus-shaped faces faces is a rhombohedron. [3] [4] An alternative name for the same shape is the trigonal deltohedron. [5]
For compounds with the formula MX 6, the chief alternative to octahedral geometry is a trigonal prismatic geometry, which has symmetry D 3h. In this geometry, the six ligands are also equivalent. There are also distorted trigonal prisms, with C 3v symmetry; a prominent example is W(CH 3) 6.
In chemistry, the trigonal prismatic molecular geometry describes the shape of compounds where six atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triangular prism. The structure commonly occurs for d 0, d 1 and d 2 transition metal complexes with covalently-bound ligands and small charge ...