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Urea-formaldehyde (UF), also known as urea-methanal, so named for its common synthesis pathway and overall structure, [1] is a nontransparent thermosetting resin or polymer. It is produced from urea and formaldehyde. These resins are used in adhesives, plywood, particle board, medium-density fibreboard (MDF), and molded objects.
Urea plant using ammonium carbamate briquettes, Fixed Nitrogen Research Laboratory, ca. 1930 Carl Bosch, 1927. The Bosch–Meiser process is an industrial process, which was patented in 1922 [1] and named after its discoverers, the German chemists Carl Bosch and Wilhelm Meiser [2] for the large-scale manufacturing of urea, a valuable nitrogenous chemical.
In 1985 the first urea-formaldehyde resin production unit was commissioned. Four of the seven current ammonia plants at Tolyatti were constructed by Chemico. [12] During the 1980s, two urea processing plants were constructed with a combined production capacity of 480,000 tons per year.
The basic reaction of urea and formaldehyde to create a urea-formaldehyde resin, followed by the condensation [12] Urea-formaldehyde resins (UF) are a class of impregnation resins for wood modification made by reacting urea with formaldehyde. This resin can be polymerized after impregnation into the wood substrate by oven-curing.
Formaldehyde is a common precursor to more complex compounds and materials. In approximate order of decreasing consumption, products generated from formaldehyde include urea formaldehyde resin, melamine resin, phenol formaldehyde resin, polyoxymethylene plastics, 1,4-butanediol, and methylene diphenyl diisocyanate. [40]
It is the largest producer of Methanol and Formaldehyde in India with production capacity of 600TPD Methanol and 325TPD Formaldehyde. The company was incorporated in 1971 and by 1976 had started production at their small methanol plant located at Namrup along with formaldehyde and a few urea-formaldehyde resins like urea-formaldehyde glue and ...
The energy consumption and greenhouse gas emissions associated with the production of Urea-formaldehyde are lower than those of Phenol formaldehyde adhesives. But Urea-formaldehyde adhesive is judged to have a nearly 50% higher life cycle impact than Phenol formaldehyde mainly because of acid based emissions during its production process. [15] [13]
The production of DMEU is through the condensation of formaldehyde with ethylene urea: [9] 2CH 2 O + (C 2 H 4 N 2 H 2)CO → (C 2 H 2 N 2 (CH 2 OH) 2)CO. The reaction proceeds around 200 °C (392 °F) but this temperature can be brought down to around 70 °C (158 °F) in the presence of an acid catalyst. [10]