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Fullerenes had been predicted for some time, but only after their accidental synthesis in 1985 were they detected in nature [3] [4] and outer space. [5] [6] The discovery of fullerenes greatly expanded the number of known allotropes of carbon, which had previously been limited to graphite, diamond, and amorphous carbon such as soot and charcoal.
In a similar fashion in 2001 it was found that the carbon allotrope fullerene, C 60 reacts with fluorine gas to give fullerene fluorides with stoichiometries up to C 60 F 48. [3] A precursor of carbon monofluoride is the fluorine-graphite intercalation compound, also called fluorine-GIC. Other intercalation fluorides of carbon are:
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