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A lanthanum hexaboride hot cathode. Lanthanum hexaboride cathodes. Lanthanum hexaboride powdered. Lanthanum hexaboride (La B 6, also called lanthanum boride and LaB) is an inorganic chemical, a boride of lanthanum. It is a refractory ceramic material that has a melting point of 2210 °C, and is insoluble in water and hydrochloric acid. [1]
When it reacts with water, lanthanum hydroxide is formed: [37] a lot of heat is evolved in the reaction and a hissing sound is heard. Lanthanum hydroxide will react with atmospheric carbon dioxide to form the basic carbonate. [38] Lanthanum fluoride is insoluble in water and can be used as a qualitative test for the presence of La 3+.
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise. The substances are listed in alphabetical order.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The CuTi 2 structure of the lanthanum, cerium and praseodymium diiodides along with HP-NdI 2 contain 4 4 nets of metal and iodine atoms with short metal-metal bonds (393-386 La-Pr). [10] these compounds should be considered to be two-dimensional metals (two-dimensional in the same way that graphite is). The salt-like dihalides include those of ...
Lanthanum oxide is a white solid that is insoluble in water, but dissolves in acidic solutions. La 2 O 3 absorbs moisture from air, converting to lanthanum hydroxide. [2] Lanthanum oxide has p-type semiconducting properties and a band gap of approximately 5.8 eV. [3]
EuFOD, an example of a europium complex. It has been known since the early 1930s that the salts of certain lanthanides are fluorescent. [4] The reaction of lanthanide salts with nucleic acids was discussed in a number of publications during the 1930s and the 1940s where lanthanum-containing reagents were employed for the fixation of nucleic acid structures. [3]
Lanthanide chlorides are a group of chemical compounds that can form between a lanthanide element (from lanthanum to lutetium) and chlorine.The lanthanides in these compounds are usually in the +2 and +3 oxidation states, although compounds with lanthanides in lower oxidation states exist.