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Cyclohexanethiol is a thiol with the formula C 6 H 11 SH. It is a colorless liquid with a strong odor. Preparation. It was first prepared by the free-radical ...
Thiols (1 C, 93 P) Pages in category "Foul-smelling chemicals" ... Cyclohexanethiol; 1,5-Cyclooctadiene; Cyclopentanecarboxylic acid; D. Decaborane; Diethyl selenide;
The −SH functional group itself is referred to as either a thiol group or a sulfhydryl group, or a sulfanyl group. Thiols are the sulfur analogue of alcohols (that is, sulfur takes the place of oxygen in the hydroxyl (−OH) group of an alcohol), and the word is a blend of "thio-" with "alcohol".
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It is a white solid, although commercial samples often appear yellow. It features the sulfenamide functional group, being a derivative of phthalimide and cyclohexanethiol. [1] In the production of synthetic rubber, CTP impedes the onset of sulfur vulcanization.
In organosulfur chemistry, the thiol-ene reaction (also alkene hydrothiolation) is an organic reaction between a thiol (R−SH) and an alkene (R 2 C=CR 2) to form a thioether (R−S−R'). This reaction was first reported in 1905, [ 1 ] but it gained prominence in the late 1990s and early 2000s for its feasibility and wide range of applications.
This reaction is rapid and stoichiometric, with the addition of one mole of thiol releasing one mole of TNB. The TNB 2− is quantified in a spectrophotometer by measuring the absorbance of visible light at 412 nm, using an extinction coefficient of 14,150 M −1 cm −1 for dilute buffer solutions, [4] [5] and a coefficient of 13,700 M −1 cm −1 for high salt concentrations, such as 6 M ...
Thiolysis is a reaction with a thiol (R-SH) that cleaves one compound into two. [1] Thiolysis involves the addition of coenzyme A to one of the products. This reaction is similar to hydrolysis, which involves water instead of a thiol. [2] This reaction is seen in β-oxidation of fatty acids. [3]