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Benzyl bromide is used in organic synthesis for the introduction of the benzyl groups when the less expensive benzyl chloride is insufficiently reactive. [6] [7] Benzylations are often achieved in the presence of catalytic amounts of sodium iodide, which generates the more reactive benzyl iodide in situ. [3]
This reagent can be used, e.g. in the reaction with carbon dioxide to prepare benzoic acid. [4] Other methods involve palladium-catalyzed coupling reactions , such as the Suzuki reaction . Bromobenzene is used as a precursor in the manufacture of phencyclidine .
Scheme 4: Lenalidomide synthesis. Lenalidomide is synthesized in a similar way using compound 3 (3-aminopiperidine-2,6-dione) treated with a nitro-substituted methyl 2-(bromomethyl) benzoate, and hydrogenation of the nitro group. [44]
Methyl benzoate is an organic compound. It is an ester with the chemical formula C 6 H 5 COOCH 3 , sometimes abbreviated as PhCO 2 Me , where Ph and Me are phenyl and methyl , respectively. Its structure is C 6 H 5 −C(=O)−O−CH 3 .
Bromomethane, commonly known as methyl bromide, is an organobromine compound with formula C H 3 Br. This colorless, odorless, nonflammable gas is produced both industrially and biologically . It is a recognized ozone-depleting chemical.
1-bromo-4-methylbenzene Molecular formula: C 7 H 7 Br (C 6 H 4 BrCH 3) Molar mass: 171.03 g/mol Appearance colorless liquid colorless liquid white crystalline solid CAS number [95-46-5] [591-17-3] [106-38-7] Properties Density and phase: 1.431 g/ml, liquid 1.4099 g/ml, liquid 1.3995 g/ml, solid Solubility in water: practically insoluble Other ...
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Methyl bromoacetate is an alkylating agent. It has been used to alkylate phenol and amino groups. [4] [5] Moreover, it can be used to make vitamins and pharmaceutical drugs. It is commonly used as a reagent in chemical modification of histidine. [2] In addition, methyl bromoacetate also use in synthesize of coumarins and cis-cyclopropane.
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