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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
The components of the sample move through the column, each at a different velocity, which are a function of specific physical interactions with the adsorbent, the stationary phase. The velocity of each component depends on its chemical nature, on the nature of the stationary phase (inside the column) and on the composition of the mobile phase.
Equation [3] involves the average velocity v + v 0 / 2 . Intuitively, the velocity increases linearly, so the average velocity multiplied by time is the distance traveled while increasing the velocity from v 0 to v, as can be illustrated graphically by plotting velocity against time as a straight line graph. Algebraically, it follows ...
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The Cambridge Handbook of Physics Formulas. Cambridge University Press. ISBN 978-0-521-57507-2. A. Halpern (1988). 3000 Solved Problems in Physics, Schaum Series. Mc Graw Hill. ISBN 978-0-07-025734-4. R.G. Lerner, G.L. Trigg (2005). Encyclopaedia of Physics (2nd ed.). VHC Publishers, Hans Warlimont, Springer. pp. 12– 13.
Hodograph transformation is a technique used to transform nonlinear partial differential equations into linear version. It consists of interchanging the dependent and independent variables in the equation to achieve linearity. [4]
This is considered one of the simplest unsteady problems that has an exact solution for the Navier–Stokes equations. [ 1 ] [ 2 ] In turbulent flow, this is still named a Stokes boundary layer, but now one has to rely on experiments , numerical simulations or approximate methods in order to obtain useful information on the flow.
For example, in fluid dynamics, the velocity field is the flow velocity, and the quantity of interest might be the temperature of the fluid. In this case, the material derivative then describes the temperature change of a certain fluid parcel with time, as it flows along its pathline (trajectory).