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Partition functions are functions of the thermodynamic state variables, such as the temperature and volume. Most of the aggregate thermodynamic variables of the system, such as the total energy, free energy, entropy, and pressure, can be expressed in terms of the partition function or its derivatives.
Probability theory. The standard probability axioms are the foundations of probability theory introduced by Russian mathematician Andrey Kolmogorov in 1933. [1] These axioms remain central and have direct contributions to mathematics, the physical sciences, and real-world probability cases. [2]
The law of total probability is [1] a theorem that states, in its discrete case, if is a finite or countably infinite set of mutually exclusive and collectively exhaustive events, then for any event. or, alternatively, [1] where, for any , if , then these terms are simply omitted from the summation since is finite.
Probability theory or probability calculus is the branch of mathematics concerned with probability. Although there are several different probability interpretations, probability theory treats the concept in a rigorous mathematical manner by expressing it through a set of axioms. Typically these axioms formalise probability in terms of a ...
Partition function (mathematics) The partition function or configuration integral, as used in probability theory, information theory and dynamical systems, is a generalization of the definition of a partition function in statistical mechanics. It is a special case of a normalizing constant in probability theory, for the Boltzmann distribution.
In probability theory and statistics, the law of the unconscious statistician, or LOTUS, is a theorem which expresses the expected value of a function g(X) of a random variable X in terms of g and the probability distribution of X. The form of the law depends on the type of random variable X in question. If the distribution of X is discrete and ...
Wald's equation. In probability theory, Wald's equation, Wald's identity[1] or Wald's lemma[2] is an important identity that simplifies the calculation of the expected value of the sum of a random number of random quantities. In its simplest form, it relates the expectation of a sum of randomly many finite-mean, independent and identically ...
Isserlis' theorem. In probability theory, Isserlis' theorem or Wick's probability theorem is a formula that allows one to compute higher-order moments of the multivariate normal distribution in terms of its covariance matrix. It is named after Leon Isserlis. This theorem is also particularly important in particle physics, where it is known as ...