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1,8-Diazabicyclo[5.4.0]undec-7-ene, or more commonly DBU, is a chemical compound and belongs to the class of amidine compounds. It is used in organic synthesis as a catalyst , a complexing ligand , and a non-nucleophilic base .
However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2, written as [Ar] 3d 4 4s 2, but whose actual configuration given in the table below is [Ar] 3d 5 4s 1.
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. Isopropanol vapor pressure (logarithmic scale) vs temperature. Drawn using data published in [ 2 ] [ 3 ]
The SI unit of molar absorption coefficient is the square metre per mole (m 2 /mol), but in practice, quantities are usually expressed in terms of M −1 ⋅cm −1 or L⋅mol −1 ⋅cm −1 (the latter two units are both equal to 0.1 m 2 /mol). In older literature, the cm 2 /mol is sometimes used; 1 M −1 ⋅cm −1 equals 1000 cm 2 /mol.
The ground state of methylene has an ionisation energy of 10.396 eV. It has a bent configuration, with H–C–H angle of 133.84°, [10] and is thus paramagnetic. (The correct prediction of this angle was an early success of ab initio quantum chemistry. [10]) However conversion to a linear configuration requires only 5.5 kcal/mol. [10]
The subjects covered in the book include: physical properties of chemicals and other materials; mathematics; thermodynamics; heat transfer; mass transfer; fluid dynamics; chemical reactors and chemical reaction kinetics; transport and storage of fluid; heat transfer equipment; psychrometry and evaporative cooling; distillation; gas absorption; liquid-liquid extraction; adsorption and ion ...
This can only be used as a very rough guide, for instance if a narrow range of wavelengths within the band 647–700 nm is absorbed, then the blue and green receptors will be fully stimulated, making cyan, and the red receptor will be partially stimulated, diluting the cyan to a greyish hue.
Chemistry stencils that used to be used for drawing equipment in lab notebooks. A laboratory notebook ( colloq. lab notebook or lab book ) is a primary record of research . Researchers use a lab notebook to document their hypotheses , experiments and initial analysis or interpretation of these experiments.