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Organic peroxides are often sold as formulations that include one or more phlegmatizing agents. That is, for safety sake or performance benefits the properties of an organic peroxide formulation are commonly modified by the use of additives to phlegmatize (desensitize), stabilize, or otherwise enhance the organic peroxide for commercial use.
Reductions with hydrosilanes are methods used for hydrogenation and hydrogenolysis of organic compounds.The approach is a subset of ionic hydrogenation.In this particular method, the substrate is treated with a hydrosilane and auxiliary reagent, often a strong acid, resulting in formal transfer of hydride from silicon to carbon. [1]
Organic redox reactions: the Birch reduction. Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds.In organic chemistry oxidations and reductions are different from ordinary redox reactions, because many reactions carry the name but do not actually involve electron transfer. [1]
α-Functionalized carbonyl compounds are reduced to the corresponding unfunctionalized carbonyl compounds in the presence of samarium(II) iodide. This process may be initiated by initial electron transfer to either the substituent at the α position or the carbonyl moiety, depending on the relative electron affinity of the functional groups.
The aluminium based Meerwein–Ponndorf–Verley reduction can be performed on prochiral ketones leading to chiral alcohols. The three main ways to achieve the asymmetric reduction is by use of a chiral alcohol hydride source, use of an intramolecular MPV reduction, or use of a chiral ligand on the aluminium alkoxide.
Ferrous compounds that contain the Fe 2+ ion, such as iron(II) sulfate; Stannous compounds that contain the Sn 2+ ion, such as tin(II) chloride; Sulfur dioxide (sometimes also used as an oxidizing agent), Sulfite compounds; Dithionates, e.g. Na 2 S 2 O 6; Thiosulfates, e.g. Na 2 S 2 O 3 (mainly in analytical chemistry) [11]
In organic chemistry, carbonyl reduction is the conversion of any carbonyl group, usually to an alcohol. It is a common transformation that is practiced in many ways. [ 1 ] Ketones , aldehydes , carboxylic acids , esters , amides , and acid halides - some of the most pervasive functional groups , -comprise carbonyl compounds.
The compound can effect regioselective conjugate reductions of various carbonyl derivatives including unsaturated aldehydes, ketones, and esters.This reagent was assigned as the "Reagent of the year" in 1991 for its functional group tolerance, high overall efficiency, and mild reaction conditions in the reduction reactions.