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The system can be flushed with an inert gas to reduce the concentration of oxygen so that when the flammable gas is admitted, an ignitable mixture cannot form. In NFPA 56, [1] this is known as purge-into-service. In combustion engineering terms, the admission of inert gas dilutes the oxygen below the limiting oxygen concentration.
Explosive charges; Flow friction: Heat generated by high velocity oxygen flow over a non-metal Note:Flow friction is a hypothesis. Flow friction has not been experimentally verified and should be considered only in conjunction with validated ignition mechanisms. Friction between relatively moving parts; Fragments from bursting vessels
For instance, to safely fill a new container or a pressure vessel with flammable gases, the atmosphere of normal air (containing 20.9 volume percent of oxygen) in the vessel would first be flushed (purged) with nitrogen or another non-flammable inert gas, thereby reducing the oxygen concentration inside the container. When the oxygen ...
Usually atmospheric air supplies the oxygen for combustion, and limits assume the normal concentration of oxygen in air. Oxygen-enriched atmospheres enhance combustion, lowering the LFL and increasing the UFL, and vice versa; an atmosphere devoid of an oxidizer is neither flammable nor explosive for any fuel concentration (except for gases that ...
The inert gas system is used to prevent the atmosphere in cargo tanks or bunkers from coming into the explosive range. [9] Inert gases keep the oxygen content of the tank atmosphere below 5% (on crude carriers, less for product carriers and gas tankers), thus making any air/hydrocarbon gas mixture in the tank too rich (too high a fuel to oxygen ...
The original mass of flammable material and the mass of the oxygen consumed (typically from the surrounding air) equals the mass of the flame products (ash, water, carbon dioxide, and other gases). Lavoisier used the experimental fact that some metals gained mass when they burned to support his ideas (because those chemical reactions capture ...
The flammability limits of the gas define those proportions, i.e. the ignitable range. In combustion engineering terms, the admission of inert gas can be said to dilute the oxygen below the limiting oxygen concentration. Inerting differs from purging. Purging, by definition, ensures that an ignitable mixture never forms. Inerting makes an ...
The explosive properties of these mixtures were discovered in Germany in 1895 by Prof. Carl von Linde, a developer of a successful machine for liquefaction of gases, who named them oxyliquits. In 1930, over 3 million pounds (1.4 × 10 ^ 6 kg) of liquid oxygen were used for this purpose in Germany alone, and additional 201,466 lb (91,383 kg ...