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It contains coupled non-linear equations that are derived from the Gibbs function. These equations are formulated in the equation of state of seawater, also called the equation of seawater. This equation relates the thermodynamic properties of the ocean (density, temperature, salinity and pressure). These equations are based on empirical ...
Temperature and salinity combine to determine the potential density of seawater; contours of constant potential density are often shown in T-S diagrams. Each contour is known as an isopycnal, or a region of constant density. These isopycnals appear curved because of the nonlinearity of the equation of state of seawater.
EOS-80 (Equation of State of Seawater -1980) uses Practical Salinity measured on the PSS-78 (Practical Salinity Scale of 1978) scale that itself is based on measurements of temperature, pressure and electrical conductivity. Thus, EOS-80 did not account for different chemical compositions of seawater. [2]
Conservative temperature is defined to be directly proportional to potential enthalpy. It is rescaled to have the same units as the in-situ temperature: = where = 3989.24495292815 J kg −1 K −1 is a reference value of the specific heat capacity, chosen to be as close as possible to the spatial average of the heat capacity over the entire ocean surface.
Annual mean sea surface salinity for the World Ocean. Data from the World Ocean Atlas 2009. [1] International Association for the Physical Sciences of the Oceans (IAPSO) standard seawater. Salinity (/ s ə ˈ l ɪ n ɪ t i /) is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is ...
Thus, they are essentially equations of state, and using the fundamental equations, experimental data can be used to determine sought-after quantities like G (Gibbs free energy) or H . [1] The relation is generally expressed as a microscopic change in internal energy in terms of microscopic changes in entropy , and volume for a closed system in ...
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.
The effect of the parcel's change in temperature due to adiabatic change in pressure (as pressure increases, temperature increases). A parcel's density may be calculated from an equation of state : ρ = ρ ( P , T , S 1 , S 2 , . . .
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