Search results
Results from the WOW.Com Content Network
Charge transfer coefficient, and symmetry factor (symbols α and β, respectively) are two related parameters used in description of the kinetics of electrochemical reactions. They appear in the Butler–Volmer equation and related expressions.
The two different mechanisms result in different charge mobilities. In disordered solids, disordered potentials result in weak localization effects (traps), which reduce the mean free path, and hence the mobility, of mobile charges. Carrier recombination also decreases mobility.
Natural or free convection is a function of Grashof and Prandtl numbers. The complexities of free convection heat transfer make it necessary to mainly use empirical relations from experimental data. [12] Heat transfer is analyzed in packed beds, nuclear reactors and heat exchangers.
The enzyme aminocyclopropane-1-carboxylic acid synthase (ACC synthase, ACS) (EC 4.4.1.14) catalyzes the synthesis of 1-Aminocyclopropane-1-carboxylic acid (ACC), a precursor for ethylene, from S-Adenosyl methionine (AdoMet, SAM), an intermediate in the Yang cycle and activated methyl cycle and a useful molecule for methyl transfer:
This is known as the charge transfer rate. The second is the rate at which reactants are provided, and products removed, from the electrode region by various processes including diffusion, migration, and convection. The latter is known as the mass-transfer rate [Note 1]. These two rates determine the concentrations of the reactants and products ...
Charge-transfer may refer to: Intervalence charge transfer; Charge-transfer complex; Charge transfer band (absorption band) Charge-exchange ionization, a form of gas ...
In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...
Allylic shifts become the dominant reaction pathway when there is substantial resistance to a normal (non-allylic) substitution. For nucleophilic substitution, such resistance is known when there is substantial steric hindrance at or around the leaving group, or if there is a geminal substituent destabilizing an accumulation of positive charge ...