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Hyperconjugation can be used to rationalize a variety of chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of exocyclic carbonyl groups, and the relative stability of substituted carbocations and substituted carbon centred radicals, and the thermodynamic Zaitsev's rule for alkene stability.
Fluid-attenuated inversion recovery (FLAIR) is a magnetic resonance imaging sequence with an inversion recovery set to null fluids. For example, it can be used in brain imaging to suppress cerebrospinal fluid (CSF) effects on the image, so as to bring out the periventricular hyperintense lesions, such as multiple sclerosis (MS) plaques. [ 1 ]
One particular method used in recent research is resting-state functional magnetic resonance imaging, rs-fMRI. In a 'reformulation' of the binary-risk vulnerability model, researchers have suggested a multiple-hit hypothesis that utilizes several risk factors — some bestowing a greater probability than others — to identify at-risk ...
Functional magnetic resonance imaging (fMRI) is a medical imaging modality that indirectly measures neural activity by observing the local hemodynamics, or blood oxygen level dependent signal (BOLD). fMRI data offers a range of insights, and can be roughly divided into two categories:
This phenomenon, a type of resonance, can stabilize the molecule or transition state. [2] It also causes an elongation of the σ-bond by adding electron density to its antibonding orbital. [1] Negative hyperconjugation is seldom observed, though it can be most commonly observed when the σ *-orbital is located on certain C–F or C–O bonds ...
In research, MEG's primary use is the measurement of time courses of activity. MEG can resolve events with a precision of 10 milliseconds or faster, while functional magnetic resonance imaging (fMRI), which depends on changes in blood flow, can at best resolve events with a precision of several hundred milliseconds. MEG also accurately ...
Functional ultrasound imaging (fUS) is a medical ultrasound imaging technique for detecting or measuring changes in neural activities or metabolism, such as brain activity loci, typically through measuring hemodynamic (blood flow) changes.
Resting state fMRI (rs-fMRI or R-fMRI), also referred to as task-independent fMRI or task-free fMRI, is a method of functional magnetic resonance imaging (fMRI) that is used in brain mapping to evaluate regional interactions that occur in a resting or task-negative state, when an explicit task is not being performed.