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Cross-polarization (CP), originally published as proton-enhanced nuclear induction spectroscopy (PENIS) [1] [2] is a solid-state nuclear magnetic resonance (ssNMR) technique to transfer nuclear magnetization from different types of nuclei via heteronuclear dipolar interactions.
Polarization can be used to filter out unwanted signals, such as jamming. If a jammer and receiver do not have the same polarization, the jamming signal will incur a loss that reduces its effectiveness. The four basic polarizations are linear horizontal, linear vertical, right-hand circular, and left-hand circular.
One consequence of this natural polarization of molecules is that 1,3- and 1,5- heteroatom substituted carbon skeletons are extremely easy to synthesize (Aldol reaction, Claisen condensation, Michael reaction, Claisen rearrangement, Diels-Alder reaction), whereas 1,2-, 1,4-, and 1,6- heteroatom substitution patterns are more difficult to access ...
Nuclear Overhauser Effect Spectroscopy (NOESY) is a 2D NMR spectroscopic method used to identify nuclear spins undergoing cross-relaxation and to measure their cross-relaxation rates. Since 1 H dipole-dipole couplings provide the primary means of cross-relaxation for organic molecules in solution, spins undergoing cross-relaxation are those ...
Consider the case of interaction of two perpendicularly polarized waves in nonlinear media with cubic nonlinearity. [1] The equations describing the self phase modulation of the fundamental wave A and the generation of new wave perpendicularly polarized wave B in condition that |B| << |A| (i.e. when the depletion of the fundamental wave is neglected, self and cross phase modulation of wave B ...
Magic-angle spinning: The sample (blue) is rotating with high frequency inside the main magnetic field (B 0). The axis of rotation is tilted by the magic angle θ m with respect to the direction of B 0. In solid-state NMR spectroscopy, magic-angle spinning (MAS) is a technique routinely used to produce better resolution NMR spectra.
Jamming during discharge of granular material is due to arch formation (red spheres) Jamming is the physical process by which the viscosity of some mesoscopic materials, such as granular materials, glasses, foams, polymers, emulsions, and other complex fluids, increases with increasing particle density.
Ab initio quantum chemistry methods are a class of computational chemistry techniques based on quantum chemistry that aim to solve the electronic Schrödinger equation. [1] Ab initio means "from first principles" or "from the beginning", meaning using only physical constants [ 2 ] and the positions and number of electrons in the system as input.