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Caprolactam molecule used to synthesize Nylon 6 by ring opening polymerization. Nylon 6 or polycaprolactam is a polymer, in particular semicrystalline polyamide.Unlike most other nylons, nylon 6 is not a condensation polymer, but instead is formed by ring-opening polymerization; this makes it a special case in the comparison between condensation and addition polymers.
One number after "PA" or "Nylon" indicates a homopolymer which is monadic or based on one amino acid (minus H 2 O) as monomer: PA 6 or Nylon 6: [NH−(CH 2) 5 −CO] n made from ε-caprolactam. Two numbers or sets of letters indicate a dyadic homopolymer formed from two monomers: one diamine and one dicarboxylic acid. The first number indicates ...
Nylon 66 (loosely written nylon 6-6, nylon 6/6, nylon 6,6, or nylon 6:6) is a type of polyamide or nylon. It, and nylon 6, are the two most common for textile and plastic industries. Nylon 66 is made of two monomers each containing 6 carbon atoms, hexamethylenediamine and adipic acid, which give nylon 66 its name. [1] Aside from its superior ...
List of some addition polymers and their uses ; Polymer Abbreviation Properties Uses Low-density polyethylene: LDPE: Chemically inert, flexible, insulator: Squeeze bottles, toys, flexible pipes, insulation cover (electric wires), six-pack rings, etc.
[1] [2] Nylon 46 is an aliphatic polyamide formed by the polycondensation of two monomers, one containing 4 carbon atoms, 1,4-diaminobutane , and the other 6 carbon atoms, adipic acid, which give nylon 46 its name. It has a higher melting point than nylon 6 or nylon 66 and mainly used in applications which must withstand high temperatures.
The Zytel product line is based mostly on nylon 66, but also includes grades based on nylon 6 as a matrix, long chain nylons such as nylon 610 (if based on at least one renewable monomer they are branded Zytel RS), and copolymers including a transparent resin called Zytel 330.
The monomers can be amides themselves (usually in the form of a cyclic lactam such as caprolactam), α,ω-amino acids or a stoichiometric mixture of a diamine and a diacid. Both these kinds of precursors give a homopolymer. Polyamides are easily copolymerized, and thus many mixtures of monomers are possible which can in turn lead to many ...
A step-growth copolymer -(-A-A-B-B-) n - formed by the condensation of two bifunctional monomers A–A and B–B is in principle a perfectly alternating copolymer of these two monomers, but is usually considered as a homopolymer of the dimeric repeat unit A-A-B-B. [6] An example is nylon 66 with repeat unit -OC-( CH 2) 4-CO-NH-(CH 2) 6-NH ...