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Fourier transform infrared spectroscopy (FTIR) [1] is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid, or gas. An FTIR spectrometer simultaneously collects high-resolution spectral data over a wide spectral range.
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms.
The schematic representation of a nano-FTIR system with a broadband infrared source. Nano-FTIR (nanoscale Fourier transform infrared spectroscopy) is a scanning probe technique that utilizes as a combination of two techniques: Fourier transform infrared spectroscopy (FTIR) and scattering-type scanning near-field optical microscopy (s-SNOM).
The particle size should be smaller than the wavelength of the incident light in order to minimize Mie scattering, so this would infer that it should be less than 5 μm for mid-infrared spectroscopy. The spectra are plotted in units of log inverse reflectance (log 1/R) versus wavenumber.
By applying intense tunable IR lasers, like IR-OPOs or IR free electron lasers, the wavelength dependence of the IRMPD yield can be studied. [5] [6] This infrared photodissociation spectroscopy allows for the measurement of vibrational spectra of (unstable) species that can only be prepared in the gas phase. Such species include molecular ions ...
Fourier-transform infrared spectroscopy is a common implementation of infrared spectroscopy. NMR also employs Fourier transforms. Gamma spectroscopy; Hadron spectroscopy studies the energy/mass spectrum of hadrons according to spin, parity, and other particle properties. Baryon spectroscopy and meson spectroscopy are types of hadron spectroscopy.
AFM-IR enables nanoscale infrared spectroscopy, [52] i.e. the ability to obtain infrared absorption spectra from nanoscale regions of a sample. Chemical compositional mapping AFM-IR can also be used to perform chemical imaging or compositional mapping with spatial resolution down to ~10-20 nm, [ 18 ] limited only by the radius of the AFM tip.
The accessibility, rapid sample turnaround and ease of use of ATR with Fourier transform infrared spectroscopy (FTIR) has led to substantial use by the scientific community. This evanescent effect only works if the crystal is made of an optical material with a higher refractive index than the sample being studied. Otherwise light is lost to the ...
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