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The fractionations of oxygen produced by sulfur disproportionation from elemental sulfur have been found to be higher, with reported values from 8 to 18.4‰, which suggests a kinetic isotope effect in the pathways involved in oxidation of elemental sulfur to sulfate, although more studies are necessary to determine what are the specific steps ...
Sulfur is metabolized by all organisms, from bacteria and archaea to plants and animals. Sulfur can have an oxidation state from -2 to +6 and is reduced or oxidized by a diverse range of organisms. [1] The element is present in proteins, sulfate esters of polysaccharides, steroids, phenols, and sulfur-containing coenzymes. [2]
Elemental sulfur is one of the oldest fungicides and pesticides. "Dusting sulfur", elemental sulfur in powdered form, is a common fungicide for grapes, strawberry, many vegetables and several other crops. It has a good efficacy against a wide range of powdery mildew diseases as well as black spot. In organic production, sulfur is the most ...
The important sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. [1]
The electron donor for the sulfur-reducing bacterium is acetate, coupled with elemental sulfur reduction to sulfide. The green sulfur bacterium produces H 2 re-oxidizing the H 2 S previously produced, in presence of light. During these cocultures experiments no elemental sulfur appears in the medium because it is immediately reduced. [64]
The energy obtained from inorganic oxidation varies depending on the substrate and the reaction. For example, the oxidation of hydrogen sulfide to elemental sulfur by ½O 2 produces far less energy (50 kcal/mol or 210 kJ/mol) than the oxidation of elemental sulfur to sulfate (150 kcal/mol or 627 kJ/mol) by 3/2 O 2,. [10]
Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. 8 MgS + 8 I 2 → S 8 + 8 MgI 2
For example, sulfur oxidation of compounds like hydrogen sulfide and elemental sulfur is performed by lithotrophic bacteria and chemosynthetic archaea. [ 69 ] [ 70 ] Most animals obtain sulfur directly from the methionine and cysteine in the protein they consume.