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Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3]
Valence shell electron pair repulsion (VSEPR) theory predicts molecule geometry. [11] [12] VSEPR predicts molecular geometry to take the configuration that allows electron pairs to be most spaced out. [11] [12] This electron distance maximization happens to achieve the most stable electron distribution. [11] [12] The result of VSEPR theory is ...
This shape is found when there are four bonds all on one central atom, with no extra unshared electron pairs. In accordance with the VSEPR (valence-shell electron pair repulsion theory), the bond angles between the electron bonds are arccos(− 1 / 3 ) = 109.47°. For example, methane (CH 4) is a tetrahedral molecule.
It is formed by the reaction of indium and bromine. [4] InBr 3 forms complexes with ligands, L, InBr 3 L, InBr 3 L 2, InBr 3 L 3. [3]Reaction with indium metal forms lower valent indium bromides, InBr 2, In 4 Br 7, In 2 Br 3, In 5 Br 7, In 7 Br 9, indium(I) bromide.
This would result in the geometry of a regular tetrahedron with each bond angle equal to arccos(− 1 / 3 ) ≈ 109.5°. However, the three hydrogen atoms are repelled by the electron lone pair in a way that the geometry is distorted to a trigonal pyramid (regular 3-sided pyramid) with bond angles
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In chemistry, pyramidal inversion (also umbrella inversion) is a fluxional process in compounds with a pyramidal molecule, such as ammonia (NH 3) "turns inside out". [1] [2] It is a rapid oscillation of the atom and substituents, the molecule or ion passing through a planar transition state. [3]
The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. p. 1722. ISBN 1-4020-3555-1. This book contains predicted electron configurations for the elements up to 172, as well as 184, based on relativistic Dirac–Fock calculations by B. Fricke in Fricke, B. (1975). Dunitz ...