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  2. Electrochemical cell - Wikipedia

    en.wikipedia.org/wiki/Electrochemical_cell

    The protons flow from the anode to the cathode through the electrolyte after the reaction. At the same time, electrons are drawn from the anode to the cathode through an external circuit, producing direct current electricity. [citation needed] cathode At the cathode, another catalyst causes hydrogen ions, electrons, and oxygen to react, forming ...

  3. Anode - Wikipedia

    en.wikipedia.org/wiki/Anode

    The terms anode and cathode are not defined by the voltage polarity of electrodes, but are usually defined by the direction of current through the electrode. An anode usually is the electrode of a device through which conventional current (positive charge) flows into the device from an external circuit, while a cathode usually is the electrode through which conventional current flows out of ...

  4. Electrochemistry - Wikipedia

    en.wikipedia.org/wiki/Electrochemistry

    The one that is smaller will be the anode and will undergo oxidation. The cell potential is then calculated as the sum of the reduction potential for the cathode and the oxidation potential for the anode. E° cell = E° red (cathode) – E° red (anode) = E° red (cathode) + E° oxi (anode)

  5. Electrolytic cell - Wikipedia

    en.wikipedia.org/wiki/Electrolytic_cell

    ) ions flow to the anode to release electrons and a hydrogen (H +) ion to produce oxygen gas in an oxidation reaction. In molten sodium chloride (NaCl), when a current is passed through the salt the anode oxidizes chloride ions (Cl −) to chlorine gas, it releases electrons to the anode. Likewise, the cathode reduces sodium ions (Na +

  6. Cathode - Wikipedia

    en.wikipedia.org/wiki/Cathode

    The cathode supplies electrons to the positively charged cations which flow to it from the electrolyte (even if the cell is galvanic, i.e., when the cathode is positive and therefore would be expected to repel the positively charged cations; this is due to electrode potential relative to the electrolyte solution being different for the anode ...

  7. Auxiliary electrode - Wikipedia

    en.wikipedia.org/wiki/Auxiliary_electrode

    The auxiliary electrode functions as a cathode whenever the working electrode is operating as an anode and vice versa. The auxiliary electrode often has a surface area much larger than that of the working electrode to ensure that the half-reaction occurring at the auxiliary electrode can occur fast enough so as not to limit the process at the ...

  8. Working electrode - Wikipedia

    en.wikipedia.org/wiki/Working_electrode

    In electrochemistry, the working electrode is the electrode in an electrochemical system on which the reaction of interest is occurring. [1] [2] [3] The working electrode is often used in conjunction with an auxiliary electrode, and a reference electrode in a three-electrode system.

  9. Half-reaction - Wikipedia

    en.wikipedia.org/wiki/Half-reaction

    At the Zn anode, oxidation takes place (the metal loses electrons). This is represented in the following oxidation half reaction (note that the electrons are on the products side): + + At the Cu cathode, reduction takes place (electrons are accepted).