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Microbial sulfate reduction has been demonstrated to fractionate sulfur isotopes in bacteria, with some studies showing a dependence upon sulfate concentration [28] and/or temperature. [64] Studies examining dozens of species of dissimilatory sulfate reducing microbes have observed sulfur isotope fractionations ranging from −65.6‰ to 0‰.
Sulfur (16 S) has 23 known isotopes with mass numbers ranging from 27 to 49, four of which are stable: 32 S (95.02%), 33 S (0.75%), 34 S (4.21%), and 36 S (0.02%). The preponderance of sulfur-32 is explained by its production from carbon-12 plus successive fusion capture of five helium-4 nuclei, in the so-called alpha process of exploding type II supernovas (see silicon burning).
The effect of major volcanic eruptions on sulfate aerosol concentrations and chemical reactions in the atmosphere. Major volcanic eruptions have an overwhelming effect on sulfate aerosol concentrations in the years when they occur: eruptions ranking 4 or greater on the Volcanic Explosivity Index inject SO 2 and water vapor directly into the stratosphere, where they react to create sulfate ...
Human-made (anthropogenic) aerosols account for about 10 percent of the total mass of aerosols in the atmosphere as estimated in 2010. The remaining 90 percent comes from natural sources such as volcanoes , dust storms , forest and grassland fires, living vegetation and sea spray , emitting particulates such as volcanic ash, desert dust, soot ...
The important sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. [1]
In forest ecosystems, sulfate is derived mostly from the atmosphere; weathering of ore minerals and evaporites contribute some sulfur. Sulfur with a distinctive isotopic composition has been used to identify pollution sources, and enriched sulfur has been added as a tracer in hydrologic studies.
The atmosphere of Earth is composed of a layer of gas mixture that surrounds the Earth's planetary surface (both lands and oceans), known collectively as air, with variable quantities of suspended aerosols and particulates (which create weather features such as clouds and hazes), all retained by Earth's gravity.
A standard atmosphere is defined by the World Meteorological Organization as "a hypothetical vertical distribution of atmospheric temperature, pressure and density which, by international agreement, is roughly representative of year-round, midlatitude conditions."