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Blast furnace gas (BFG) [1] is a by-product of blast furnaces that is generated when the iron ore is reduced with coke to metallic iron. It has a very low heating value , about 3.5 MJ/m 3 (93 BTU /cu.ft), [ 2 ] because it consists of about 51 vol% nitrogen and 22 vol% carbon dioxide , which are not flammable.
Blast furnaces differ from bloomeries and reverberatory furnaces in that in a blast furnace, flue gas is in direct contact with the ore and iron, allowing carbon monoxide to diffuse into the ore and reduce the iron oxide. The blast furnace operates as a countercurrent exchange process whereas a bloomery does not.
In the temperature ranges commonly used, the metal and the oxide are in a condensed state (solid or liquid), and oxygen is a gas with a much larger molar entropy. For the oxidation of each metal, the dominant contribution to the entropy change (ΔS) is the removal of 1 ⁄ 2 mol O 2, so that ΔS is negative and roughly equal for all metals.
For blast furnaces, direct reduction corresponds to the reduction of oxides by the carbon in the coke. However, in practice, direct reduction only plays a significant role in the final stage of iron reduction in a blast furnace, by helping to reduce wustite (FeO) to iron. In this case, the chemical reaction can be trivially described as follows ...
The internal operating temperature of the water jacket furnace is lower than that of a blast furnace used to make iron, and the process does not depend upon the formation of a bosh shell, as is critical in the operation of a blast furnace making iron. Conventional blast furnaces used for smelting iron ore use a hot blast.
The HIsarna ironmaking process is a direct reduced iron process for iron making in which iron ore is processed almost directly into liquid iron ().The process combines two process units, the Cyclone Converter Furnace (CCF) for ore melting and pre-reduction and a Smelting Reduction Vessel (SRV) where the final reduction stage to liquid iron takes place.
The coking plant that feeds a battery of blast furnaces is just as expensive as the blast furnace and requires a specific quality of coal. [ 64 ] [ 65 ] Conversely, many direct-reduction processes are disadvantaged by the costly transformation of ore into pellets: these cost on average 70% more than raw ore. [ 66 ]
James Beaumont Neilson, previously foreman at Glasgow gas works, invented the system of preheating the blast for a furnace.He found that by increasing the temperature of the incoming air to 149 °C (300 °F), he could reduce the fuel consumption from 8.06 tons of coal to 5.16 tons of coal per ton of produced iron with further reductions at even higher temperatures. [4]