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  2. Energy operator - Wikipedia

    en.wikipedia.org/wiki/Energy_operator

    In quantum mechanics, energy is defined in terms of the energy operator, ... wave function of a quantum system. The solution of the Schrödinger equation for a ...

  3. Hamiltonian (quantum mechanics) - Wikipedia

    en.wikipedia.org/.../Hamiltonian_(quantum_mechanics)

    In quantum mechanics, the Hamiltonian of a system is an operator corresponding to the total energy of that system, including both kinetic energy and potential energy.Its spectrum, the system's energy spectrum or its set of energy eigenvalues, is the set of possible outcomes obtainable from a measurement of the system's total energy.

  4. Quantum harmonic oscillator - Wikipedia

    en.wikipedia.org/wiki/Quantum_harmonic_oscillator

    For this reason, a is called an annihilation operator ("lowering operator"), and a † a creation operator ("raising operator"). The two operators together are called ladder operators . Given any energy eigenstate, we can act on it with the lowering operator, a , to produce another eigenstate with ħω less energy.

  5. Molecular Hamiltonian - Wikipedia

    en.wikipedia.org/wiki/Molecular_Hamiltonian

    In general, the classical kinetic energy T defines the metric tensor g = (g ij) associated with the curvilinear coordinates s = (s i) through = ˙ ˙. The quantization step is the transformation of this classical kinetic energy into a quantum mechanical operator.

  6. Schrödinger equation - Wikipedia

    en.wikipedia.org/wiki/Schrödinger_equation

    Bohmian mechanics reformulates quantum mechanics to make it deterministic, at the price of adding a force due to a "quantum potential". It attributes to each physical system not only a wave function but in addition a real position that evolves deterministically under a nonlocal guiding equation.

  7. Free particle - Wikipedia

    en.wikipedia.org/wiki/Free_particle

    The solution for a particle with momentum p or wave vector k, ... the total energy E is equal to the kinetic energy, ... Quantum mechanics, E. Zaarur, ...

  8. Kinetic energy - Wikipedia

    en.wikipedia.org/wiki/Kinetic_energy

    In quantum mechanics, observables like kinetic energy are represented as operators. For one particle of mass m, the kinetic energy operator appears as a term in the Hamiltonian and is defined in terms of the more fundamental momentum operator ^. The kinetic energy operator in the non-relativistic case can be written as

  9. Hellmann–Feynman theorem - Wikipedia

    en.wikipedia.org/wiki/Hellmann–Feynman_theorem

    These quantum numbers are usually independent, but here the solutions must be varied so as to keep the number of nodes in the wavefunction fixed. The number of nodes is n − l − 1 {\displaystyle n-l-1} , so ∂ n / ∂ l = 1 {\displaystyle \partial n/\partial l=1} .