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  2. Aromatization - Wikipedia

    en.wikipedia.org/wiki/Aromatization

    Aromatization is a chemical reaction in which an aromatic system is formed from a single nonaromatic precursor. Typically aromatization is achieved by dehydrogenation of existing cyclic compounds, illustrated by the conversion of cyclohexane into benzene. Aromatization includes the formation of heterocyclic systems. [1]

  3. Cyclohexane - Wikipedia

    en.wikipedia.org/wiki/Cyclohexane

    Cyclohexane is a cycloalkane with the ... Producers of cyclohexane account for approximately 11.4% of global demand for benzene. [8] The reaction is highly exothermic ...

  4. Benzene - Wikipedia

    en.wikipedia.org/wiki/Benzene

    The most common reactions of benzene involve substitution of a proton by other groups. [72] Electrophilic aromatic substitution is a general method of derivatizing benzene. Benzene is sufficiently nucleophilic that it undergoes substitution by acylium ions and alkyl carbocations to give substituted derivatives.

  5. Resonance (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Resonance_(chemistry)

    The complete hydrogenation of benzene to cyclohexane via 1,3-cyclohexadiene and cyclohexene is exothermic; 1 mole of benzene delivers 208.4 kJ (49.8 kcal). Hydrogenation of one mole of double bonds delivers 119.7 kJ (28.6 kcal), as can be deduced from the last step, the hydrogenation of cyclohexene.

  6. Birch reduction - Wikipedia

    en.wikipedia.org/wiki/Birch_reduction

    Birch reduction of benzene, also available in animated form. The reaction is known to be third order – first order in the aromatic, first order in the alkali metal, and first order in the alcohol. [4] This requires that the rate-limiting step be the conversion of radical anion B to the cyclohexadienyl radical C. Birch reduction of anisole.

  7. Cyclohexa-1,3-diene - Wikipedia

    en.wikipedia.org/wiki/Cyclohexa-1,3-diene

    Useful reactions of this diene are cycloadditions, such as the Diels-Alder reaction. [2] Conversion of cyclohexa-1,3-diene to benzene + hydrogen is exothermic by about 25 kJ/mol in the gas phase. [3] [4] cyclohexane → cyclohexa-1,3-diene + 2 H 2 (ΔH = +231.5 kJ/mol; endothermic) cyclohexanebenzene + 3 H 2 (ΔH = +205 kJ/mol; endothermic)

  8. Bergman cyclization - Wikipedia

    en.wikipedia.org/wiki/Bergman_cyclization

    The reaction product is a derivative of benzene. Scheme 1. Bergman cyclization. The reaction proceeds by a thermal reaction or pyrolysis (above 200 °C) forming a short-lived and very reactive para-benzyne biradical species. It will react with any hydrogen donor such as 1,4-cyclohexadiene which converts to benzene.

  9. Cyclohexene - Wikipedia

    en.wikipedia.org/wiki/Cyclohexene

    Benzene is converted to cyclohexylbenzene by acid-catalyzed alkylation with cyclohexene. [6] Cyclohexylbenzene is a precursor to both phenol and cyclohexanone. [7] Hydration of cyclohexene gives cyclohexanol, which can be dehydrogenated to give cyclohexanone, a precursor to caprolactam. [8] The oxidative cleavage of cyclohexene gives adipic acid.