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Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4.Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).
Bisulfide (or bisulphide in British English) is an inorganic anion with the chemical formula HS − (also written as SH −). It contributes no color to bisulfide salts, and its salts may have a distinctive putrid smell. It is a strong base. Bisulfide solutions are corrosive and attack the skin.
The bisulfite anion exists in solution as a mixture of two tautomers. One tautomer has the proton attached to one of the three oxygen atoms. In the second tautomer the proton resides on sulfur. The S-protonated tautomer has C 3v symmetry. The O-protonated tautomer has only C s symmetry.
Ammonium sulfate decomposes upon heating above 250 °C (482 °F), first forming ammonium bisulfate. Heating at higher temperatures results in decomposition into ammonia, nitrogen, sulfur dioxide, and water. [17] As a salt of a strong acid (H 2 SO 4) and weak base (NH 3), its solution is acidic; the pH of 0.1 M solution is 5.5.
Although the equilibrium lies far to the left, evaporation of a bisulfite salt will produce a substantial amount of disulfite. [6] Disulfite is the conjugate base of disulfurous acid (pyrosulfurous acid), which originates from sulfurous acid in accordance with the dehydration reaction above: 2 H 2 SO 3 → 2 HSO − 3 + 2 H + → H 2 S 2 O 5 ...
The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, HSO − 4, which is in turn the conjugate base of H 2 SO 4, sulfuric acid. Organic sulfate esters , such as dimethyl sulfate , are covalent compounds and esters of sulfuric acid.
A space-filling model of the sulfite anion. Sulfites or sulphites are compounds that contain the sulfite ion (systematic name: sulfate(IV) ion), SO 2− 3. The sulfite ion is the conjugate base of bisulfite. Although its acid (sulfurous acid) is elusive, [1] its salts are widely used.
Ammonium bisulfate, also known as ammonium hydrogen sulfate, is a white, crystalline solid with the formula (NH 4)HSO 4. This salt is the product of the half-neutralization of sulfuric acid by ammonia .