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Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
Conversely, decreasing temperature would also make some water condense, again making the final volume deviating from predicted by the ideal gas law. Therefore, gas volume may alternatively be expressed excluding the humidity content: V d (volume dry). This fraction more accurately follows the ideal gas law. On the contrary, V s (volume ...
The standard unit is the meter cubed per kilogram (m 3 /kg or m 3 ·kg −1). Sometimes specific volume is expressed in terms of the number of cubic centimeters occupied by one gram of a substance. In this case, the unit is the centimeter cubed per gram (cm 3 /g or cm 3 ·g −1). To convert m 3 /kg to cm 3 /g, multiply by 1000; conversely ...
As noted, the much lower values for gas heat capacity in terms of volume as compared with solids (although more comparable per mole, see below) results mostly from the fact that gases under standard conditions consist of mostly empty space (about 99.9% of volume), which is not filled by the atomic volumes of the atoms in the gas. Since the ...
The lifting force for a volume of gas is given by the equation: F B = (ρ air - ρ gas) × g × V. Where F B = Buoyant force (in newton); g = gravitational acceleration = 9.8066 m/s 2 = 9.8066 N/kg; V = volume (in m 3). The amount of mass that can be lifted by hydrogen in air per unit volume at sea level, equal to the density difference between ...
It also denotes the ratio of equivalent air volume drawn into the cylinder to the cylinder's swept volume. [5] This equivalent volume is commonly inserted into a mass estimation equation based upon Boyle's Gas Law. When VE is multiplied by the cylinder volume, an accurate estimate of cylinder air mass (charge) can be made for use in determining ...
The standard temperature and pressure (STP) for gas varies depending on the particular code being used. [2] It is just as important to know the standard pressure as the temperature. Formerly, OPEC used 101.325 kPa (14.696 psia) but now the standard is 101.560 kPa (14.73 psia).