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  2. Phenylboronic acid - Wikipedia

    en.wikipedia.org/wiki/Phenylboronic_acid

    Phenylboronic acid or benzeneboronic acid, abbreviated as PhB(OH) 2 where Ph is the phenyl group C 6 H 5 - and B(OH) 2 is a boronic acid containing a phenyl substituent and two hydroxyl groups attached to boron. Phenylboronic acid is a white powder and is commonly used in organic synthesis.

  3. Hell–Volhard–Zelinsky halogenation - Wikipedia

    en.wikipedia.org/wiki/Hell–Volhard–Zelinsky...

    An example of the Hell–Volhard–Zelinsky reaction can be seen in the preparation of alanine from propionic acid.In the first step, a combination of bromine and phosphorus tribromide is used in the Hell–Volhard–Zelinsky reaction to prepare 2-bromopropionic acid, [3] which in the second step is converted to a racemic mixture of the amino acid product by ammonolysis.

  4. Fluorobenzene - Wikipedia

    en.wikipedia.org/wiki/Fluorobenzene

    PhN=N-N(CH 2) 5 + 2 HF → PhF + N 2 + [(CH 2) 5 NH 2]F. Historical note: in Wallach's era, the element fluorine was symbolized with "Fl". Thus, his procedure is subtitled "Fluorbenzol, C 6 H 5 Fl". [1] On the laboratory scale, PhF is prepared by the thermal decomposition of the benzenediazonium tetrafluoroborate: PhN 2 BF 4 → PhF + BF 3 + N 2

  5. Sandmeyer reaction - Wikipedia

    en.wikipedia.org/wiki/Sandmeyer_reaction

    The most commonly employed Sandmeyer reactions are the chlorination, bromination, cyanation, and hydroxylation reactions using CuCl, CuBr, CuCN, and Cu 2 O, respectively. More recently, trifluoromethylation of diazonium salts has been developed and is referred to as a 'Sandmeyer-type' reaction.

  6. 1-Bromo-4-fluorobenzene - Wikipedia

    en.wikipedia.org/wiki/1-Bromo-4-fluorobenzene

    4-Fluorobromobenzene is synthesized via bromination of fluorobenzene in the presence of a Lewis acid catalyst such as iron(III) bromide or aluminium tribromide. [2]4-Bromofluorobenzene is regarded by the Toxic Substances Control Act as a high production volume chemical, that is, a chemical that 1 million pounds (about 500 tonnes) per year is either produced in or imported to the United States.

  7. Bromobenzene - Wikipedia

    en.wikipedia.org/wiki/Bromobenzene

    This reagent can be used, e.g. in the reaction with carbon dioxide to prepare benzoic acid. [4] Other methods involve palladium-catalyzed coupling reactions, such as the Suzuki reaction. Bromobenzene is used as a precursor in the manufacture of phencyclidine.

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  9. Bromofluoromethane - Wikipedia

    en.wikipedia.org/wiki/Bromofluoromethane

    Bromofluoromethane is a mixed gaseous halomethane soluble in alcohol and very soluble in chloroform. Its standard molar entropy , S o gas is 276.3 J/(mol K) and heat capacity , c p is 49.2 J/(mol K).