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  2. Antarafacial and suprafacial - Wikipedia

    en.wikipedia.org/wiki/Antarafacial_and_suprafacial

    For a σ bond, it corresponds to involvement of one "interior" lobe and one "exterior" lobe of the bond. The relationship is suprafacial when the same face of the π system or isolated orbital are involved in the process (think syn). For a σ bond, it corresponds to involvement of two "interior" lobes or two "exterior" lobes of the bond.

  3. Carbon–carbon bond - Wikipedia

    en.wikipedia.org/wiki/Carbon–carbon_bond

    Carbon is one of the few elements that can form long chains of its own atoms, a property called catenation.This coupled with the strength of the carbon–carbon bond gives rise to an enormous number of molecular forms, many of which are important structural elements of life, so carbon compounds have their own field of study: organic chemistry.

  4. Spiro compound - Wikipedia

    en.wikipedia.org/wiki/Spiro_compound

    A spiro compound, or spirane, from the Latin spīra, meaning a twist or coil, [22] [5]: 1138 [23] is a chemical compound, typically an organic compound, that presents a twisted structure of two or more rings (a ring system), in which 2 or 3 rings are linked together by one common atom, [2]: SP-0

  5. Topological index - Wikipedia

    en.wikipedia.org/wiki/Topological_index

    The simplest topological indices do not recognize double bonds and atom types (C, N, O etc.) and ignore hydrogen atoms ("hydrogen suppressed") and defined for connected undirected molecular graphs only. [5] More sophisticated topological indices also take into account the hybridization state of each of the atoms contained in the molecule.

  6. Carbon–nitrogen bond - Wikipedia

    en.wikipedia.org/wiki/Carbon–nitrogen_bond

    A carbon–nitrogen bond is a covalent bond between carbon and nitrogen and is one of the most abundant bonds in organic chemistry and biochemistry. [ 1 ] Nitrogen has five valence electrons and in simple amines it is trivalent , with the two remaining electrons forming a lone pair .

  7. Double bond - Wikipedia

    en.wikipedia.org/wiki/Double_bond

    Other common double bonds are found in azo compounds (N=N), imines (C=N), and sulfoxides (S=O). In a skeletal formula, a double bond is drawn as two parallel lines (=) between the two connected atoms; typographically, the equals sign is used for this. [1] [2] Double bonds were introduced in chemical notation by Russian chemist Alexander Butlerov.

  8. Terminal alkene - Wikipedia

    en.wikipedia.org/wiki/Terminal_alkene

    The double bond of an alpha olefin is between the #1 and #2 (IUPAC) or α and β (common) carbon atoms. In organic chemistry , terminal alkenes ( alpha-olefins , α-olefins , or 1-alkenes ) are a family of organic compounds which are alkenes (also known as olefins) with a chemical formula C x H 2 x , distinguished by having a double bond at the ...

  9. Bridging ligand - Wikipedia

    en.wikipedia.org/wiki/Bridging_ligand

    For doubly bridging (μ 2-) ligands, two limiting representation are 4-electron and 2-electron bonding interactions. These cases are illustrated in main group chemistry by [Me 2 Al(μ 2-Cl)] 2 and [Me 2 Al(μ 2-Me)] 2. Complicating this analysis is the possibility of metal–metal bonding.