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A carbanion is one of several reactive intermediates in organic chemistry. In organic synthesis, organolithium reagents and Grignard reagents are commonly treated and referred to as "carbanions." This is a convenient approximation, although these species are generally clusters or complexes containing highly polar, but still covalent bonds metal ...
In organic chemistry, methenium (also called methylium, carbenium, [2] methyl cation, or protonated methylene) is a cation with the formula CH + 3.
It was the heptamethylbenzenium ion, made by treating hexamethylbenzene with methyl chloride and aluminium chloride. The stable 7-norbornadienyl cation was prepared by Story et al. in 1960 [15] by reacting norbornadienyl chloride with silver tetrafluoroborate in sulfur dioxide at −80 °C.
The 2-Norbornyl cation is one of the best characterized carbonium ion. It is the prototype for non-classical ions. As indicated first by low-temperature NMR spectroscopy and confirmed by X-ray crystallography, [1] it has a symmetric structure with an RCH 2 + group bonded to an alkene group, stabilized by a bicyclic structure.
Primary carbocations in the solution phase, even as transient intermediates (the ethyl cation has been proposed for reactions in 99.9% sulfuric acid and in FSO 2 OH·SbF 5), [12] and methyl cation has only been unambiguously identified in the gas phase. In most, if not all cases, the ground state of alleged primary carbenium ions consist of ...
The oxidation products derived from methyl are hydroxymethyl group −CH 2 OH, formyl group −CHO, and carboxyl group −COOH. For example, permanganate often converts a methyl group to a carboxyl (−COOH) group, e.g. the conversion of toluene to benzoic acid. Ultimately oxidation of methyl groups gives protons and carbon dioxide, as seen in ...
A ketone compound containing a carbonyl group (C=O) For organic chemistry, a carbonyl group is a functional group with the formula C=O, composed of a carbon atom double-bonded to an oxygen atom, and it is divalent at the C atom.
In the reaction mechanism, there is 1 as the nucleophile: [3]. Deprotonation of 1 by a base leads to carbanion 2, stabilized by its electron-withdrawing groups.Structures 2a to 2c are three resonance structures that can be drawn for this species, two of which have enolate ions.