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The phase composition of a particular cement can be quantified through a complex set of calculation known as the Bogue formula. To avoid the flash setting of concrete, due to the very fast hydration of the tricalcium aluminate ( C 3 A ), 2–5 wt. % calcium sulfate is interground with the cement clinker to prepare the cement powder.
An AFm phase is an "alumina, ferric oxide, monosubstituted" phase, or aluminate ferrite monosubstituted, or Al 2 O 3, Fe 2 O 3 mono, in cement chemist notation (CCN). AFm phases are important hydration products in the hydration of Portland cements and hydraulic cements.
The effect of the water-to-cement (w/c) ratio onto the mechanical strength of concrete was first studied by René Féret (1892) in France, and then by Duff A. Abrams (1918) (inventor of the concrete slump test) in the USA, and by Jean Bolomey (1929) in Switzerland.
Its forms an impure solid solution that deviates markedly in composition from the simple chemical formula. The calcium aluminoferrite phase acts as a repository for many of the minor elements in the clinker. Most of the transition metals in the cement are found in the ferrite phase, notably titanium, manganese and zinc.
Calcium aluminates can form complex salts in combination with different types of anions.Two series of calcium aluminates are known in cement chemistry: AFm and AFt phases, being respectively mono- or tri-substituted with a given divalent anion X (e.g. SO 2− 4, CO 2− 3, or hosting a divalent impurity such as SeO 2− 4 [3]...), or with two units of a monovalent anion, e.g. OH −, Cl − ...
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Concrete has a very low coefficient of thermal expansion, and as it matures concrete shrinks. All concrete structures will crack to some extent, due to shrinkage and tension. Concrete which is subjected to long-duration forces is prone to creep. The density of concrete varies, but is around 2,400 kilograms per cubic metre (150 lb/cu ft). [1]
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