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Bromobenzene is an aryl bromide and the simplest of the bromobenzenes, consisting of a benzene ring substituted with one bromine atom. Its chemical formula is C 6 H 5 Br . It is a colourless liquid although older samples can appear yellow.
Phenol: 181.75 3.60 43.0 –7.27 K f [2] K b [1] Water: 100.00 0.512 0.00 –1.86 K b & K f [2] Ethyl Acetate: 77.1 [5] Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7] Acetonitrile: 0.78 81.6 −45 [8] Heptane: 98.4 [9] Isobutanol: 107.7 [10] n-Hexane: 0.66 68.7 [11] n-Butanol: 117.7 [12] Hydrochloric Acid: 84.8 [13] tert ...
Chemical structure of 2-bromophenol. A bromophenol is an organic compound consisting of hydroxyl groups and bromine atoms bonded to a benzene ring. They may be viewed as hydroxyl derivatives of bromobenzene, or as brominated derivatives of phenol.
IUPAC name: 2-Bromophenol: 3-Bromophenol: 4-Bromophenol: Other names o-Bromophenol: m-Bromophenol: p-Bromophenol Chemical structure: CAS number: 95-56-7: 591-20-8: 106-41-2 PubChem ID CID 7244 from PubChem: CID 11563 from PubChem: CID 7808 from PubChem: Chemical formula: C 6 H 5 BrO Molar mass: 173.02 g/mol 1: Physical state: liquid solid ...
This is in contrast to the classical procedure (known by the German name Verkochung ), which calls for boiling the diazonium salt in aqueous acid, a process that is believed to involve the aryl cation instead of radical and is known to generate other nucleophilic addition side products in addition to the desired hydroxylation product.
Phenol is an ortho/para director, but in a presence of base, the reaction is more rapid. It is due to the higher reactivity of phenolate anion. The negative oxygen was 'forced' to give electron density to the carbons (because it has a negative charge, it has an extra +I effect).
Unlike the Gattermann reaction, this reaction is not applicable to phenol and phenol ether substrates. [5] Although the highly unstable formyl chloride was initially postulated as an intermediate, formyl cation (i.e., protonated carbon monoxide), [HCO] + , is now thought to react directly with the arene without the initial formation of formyl ...
Bromobenzenes may be carboxylated into carboxylic acids using carbon monoxide.The reaction takes place in a two-phase mixture of p-xylene and water as solvent, in the presence of catalytic PdCl