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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
Bohr calculated that a 1s orbital electron of a hydrogen atom orbiting at the Bohr radius of 0.0529 nm travels at nearly 1/137 the speed of light. [11] One can extend this to a larger element with an atomic number Z by using the expression v ≈ Z c 137 {\displaystyle v\approx {\frac {Zc}{137}}} for a 1s electron, where v is its radial velocity ...
The fine-structure constant gives the maximum positive charge of an atomic nucleus that will allow a stable electron-orbit around it within the Bohr model (element feynmanium). [20] For an electron orbiting an atomic nucleus with atomic number Z the relation is mv 2 / r = 1 / 4πε 0 Ze 2 / r 2 .
The model's key success lay in explaining the Rydberg formula for the spectral emission lines of atomic hydrogen by using the transitions of electrons between orbits. [24]: 276 While the Rydberg formula had been known experimentally, it did not gain a theoretical underpinning until the Bohr model was introduced. Not only did the Bohr model ...
Bohr was one of the most vocal opponents of the photon idea and did not openly embrace it until 1925. [8] The photon appealed to Einstein because he saw it as a physical reality (although a confusing one) behind the numbers presented by Planck mathematically in 1900. Bohr disliked it because it made the choice of mathematical solution arbitrary.
However, a more accurate model takes into account relativistic and spin effects, which break the degeneracy of the energy levels and split the spectral lines. The scale of the fine structure splitting relative to the gross structure energies is on the order of ( Zα ) 2 , where Z is the atomic number and α is the fine-structure constant , a ...
Atomic orbitals are basic building blocks of the atomic orbital model (or electron cloud or wave mechanics model), a modern framework for visualizing submicroscopic behavior of electrons in matter. In this model, the electron cloud of an atom may be seen as being built up (in approximation) in an electron configuration that is a product of ...
In a 1960 review of Heisenberg's book, Bohr's close collaborator Léon Rosenfeld called the term an "ambiguous expression" and suggested it be discarded. [22] However, this did not come to pass, and the term entered widespread use. [16] [19] Bohr's ideas in particular are distinct despite the use of his Copenhagen home in the name of the ...