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The wave equation is a second-order linear partial differential equation for the description of waves or standing wave fields such as mechanical waves (e.g. water waves, sound waves and seismic waves) or electromagnetic waves (including light waves). It arises in fields like acoustics, electromagnetism, and fluid dynamics.
The phase velocity is the rate at which the phase of the wave propagates in space. The group velocity is the rate at which the wave envelope, i.e. the changes in amplitude, propagates. The wave envelope is the profile of the wave amplitudes; all transverse displacements are bound by the envelope profile.
In this theory, the wave equations and the wave functions have their place, but in a somewhat different guise. The main objects of interest are not the wave functions, but rather operators, so called field operators (or just fields where "operator" is understood) on the Hilbert space of states (to be described next section). It turns out that ...
In a mathematical sense, these wave functions are the basis set of functions, the basis functions, which describe the electrons of a given atom. In chemical reactions, orbital wavefunctions are modified, i.e. the electron cloud shape is changed, according to the type of atoms participating in the chemical bond.
In quantum chemistry and molecular physics, the Born–Oppenheimer (BO) approximation is the best-known mathematical approximation in molecular dynamics. Specifically, it is the assumption that the wave functions of atomic nuclei and electrons in a molecule can be treated separately, based on the fact that the nuclei are much heavier than the electrons.
A one-way wave equation is a first-order partial differential equation describing one wave traveling in a direction defined by the vector wave velocity. It contrasts with the second-order two-way wave equation describing a standing wavefield resulting from superposition of two waves in opposite directions (using the squared scalar wave velocity).
For example, in a collision between electrons and molecules, there may be tens or hundreds of particles involved. But the phenomenon may be reduced to a two-body problem by describing all the molecule constituent particle potentials together with a pseudopotential. [5] In these cases, the Lippmann–Schwinger equations may be used.
When these approaches are compared, the use of the Schrödinger equation is sometimes called "wave mechanics". The Klein-Gordon equation is a wave equation which is the relativistic version of the Schrödinger equation. The Schrödinger equation is nonrelativistic because it contains a first derivative in time and a second derivative in space ...