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In physics, mass–energy equivalence is the relationship between mass and energy in a system's rest frame, where the two quantities differ only by a multiplicative constant and the units of measurement. [1][2] The principle is described by the physicist Albert Einstein 's formula: . [3] In a reference frame where the system is moving, its ...
In 1884, Jacobus van 't Hoff proposed the Van 't Hoff equation describing the temperature dependence of the equilibrium constant for a reversible reaction: = where ΔU is the change in internal energy, K is the equilibrium constant of the reaction, R is the universal gas constant, and T is thermodynamic temperature.
In the Arrhenius equation, the term activation energy (Ea) is used to describe the energy required to reach the transition state, and the exponential relationship k = A exp (−Ea/RT) holds. In transition state theory, a more sophisticated model of the relationship between reaction rates and the transition state, a superficially similar ...
For Faraday's first law, M, F, v are constants; thus, the larger the value of Q, the larger m will be. For Faraday's second law, Q, F, v are constants; thus, the larger the value of (equivalent weight), the larger m will be. In the simple case of constant- current electrolysis, Q = It, leading to. and then to. where: t is the total time the ...
Chapman–Jouguet condition. The Chapman–Jouguet condition holds approximately in detonation waves in high explosives. It states that the detonation propagates at a velocity at which the reacting gases just reach sonic velocity (in the frame of the leading shock wave) as the reaction ceases. [1][2] David Chapman [3] and Émile Jouguet [4 ...
In mathematics, an equivalence relation is a binary relation that is reflexive, symmetric and transitive. The equipollence relation between line segments in geometry is a common example of an equivalence relation. A simpler example is equality. Any number is equal to itself (reflexive). If , then (symmetric).
The Higgs mechanism occurs whenever a charged field has a vacuum expectation value. In the non-relativistic context this is a superconductor, more formally known as the Landau model of a charged Bose–Einstein condensate. In the relativistic condensate, the condensate is a scalar field that is relativistically invariant.
The Eyring equation (occasionally also known as Eyring–Polanyi equation) is an equation used in chemical kinetics to describe changes in the rate of a chemical reaction against temperature. It was developed almost simultaneously in 1935 by Henry Eyring, Meredith Gwynne Evans and Michael Polanyi. The equation follows from the transition state ...