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Even more generally, it holds that a general solution to the Schrödinger equation can be found by taking a weighted sum over a basis of states. A choice often employed is the basis of energy eigenstates, which are solutions of the time-independent Schrödinger equation.
which is an eigenvalue equation. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. However, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies, or eigenvalues, can be found.
Thus the solutions () are just the Legendre functions ( ()) with =, and =,,, =,,,,. Moreover, eigenvalues and scattering data can be explicitly computed. [ 3 ] In the special case of integer λ {\displaystyle \lambda } , the potential is reflectionless and such potentials also arise as the N-soliton solutions of the Korteweg–De Vries ...
In quantum mechanics and scattering theory, the one-dimensional step potential is an idealized system used to model incident, reflected and transmitted matter waves.The problem consists of solving the time-independent Schrödinger equation for a particle with a step-like potential in one dimension.
Non-relativistic time-independent Schrödinger equation [ edit ] Summarized below are the various forms the Hamiltonian takes, with the corresponding Schrödinger equations and forms of wavefunction solutions.
Three wavefunction solutions to the time-dependent Schrödinger equation for a harmonic oscillator. Left: The real part (blue) and imaginary part (red) of the wavefunction. Right: The probability of finding the particle at a certain position.
The time-independent Schrödinger equation for the wave function () reads ^ = [+ ()] = where ^ is the Hamiltonian, is the (reduced) Planck constant, is the mass, the energy of the particle and = [() ()] is the barrier potential with height > and width .
The main effort in this approximate solution of the nuclear motion Schrödinger equation is the computation of the Hessian F of V and its diagonalization. This approximation to the nuclear motion problem, described in 3 N mass-weighted Cartesian coordinates, became standard in quantum chemistry , since the days (1980s-1990s) that algorithms for ...