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which is an eigenvalue equation. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. However, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies, or eigenvalues, can be found.
Even more generally, it holds that a general solution to the Schrödinger equation can be found by taking a weighted sum over a basis of states. A choice often employed is the basis of energy eigenstates, which are solutions of the time-independent Schrödinger equation.
Thus the solutions () are just the Legendre functions ( ()) with =, and =,,, =,,,,. Moreover, eigenvalues and scattering data can be explicitly computed. [ 3 ] In the special case of integer λ {\displaystyle \lambda } , the potential is reflectionless and such potentials also arise as the N-soliton solutions of the Korteweg–De Vries ...
The time-independent Schrödinger equation for the wave function is ^ = [+ ()] = (), where Ĥ is the Hamiltonian, ħ is the reduced Planck constant, m is the mass, E the energy of the particle. The step potential is simply the product of V 0 , the height of the barrier, and the Heaviside step function : V ( x ) = { 0 , x < 0 V 0 , x ≥ 0 ...
Non-relativistic time-independent Schrödinger equation [ edit ] Summarized below are the various forms the Hamiltonian takes, with the corresponding Schrödinger equations and forms of wavefunction solutions.
In quantum mechanics, the Schrödinger equation describes how a system changes with time. It does this by relating changes in the state of the system to the energy in the system (given by an operator called the Hamiltonian). Therefore, once the Hamiltonian is known, the time dynamics are in principle known.
Three wavefunction solutions to the time-dependent Schrödinger equation for a harmonic oscillator. Left: The real part (blue) and imaginary part (red) of the wavefunction. Right: The probability of finding the particle at a certain position.
The time-independent Schrödinger equation for the wave function () reads ^ = [+ ()] = where ^ is the Hamiltonian, is the (reduced) Planck constant, is the mass, the energy of the particle and = [() ()] is the barrier potential with height > and width .